Complexe相关论文
Construction and Photoluminescence Properties of Zn(Ⅱ)/Cd(Ⅱ) Complexes with 4-Amino-3,5-propyl-1,2,4
Reaction of ZnCl2 and 4-amino-3,5-propyl-1,2,4-triazole(dpatrz) or CdCl2, NaN3 and dpatrz, in aqueous solution at room t......
The macrocyclic ligand -H2 py N2-O3ane(2) was readily prepared in a diluted condition in THF.The mixture of 2 and Ni(O......
In this study,a series of Co_3O_4/ mildly oxidized graphite oxide(mGO) nanocatalysts(Co_3O_4/ mGO-l,Co_3O_4/ mGO-2 and C......
In the past thirty years,transition metal catalyzed silylation of inert C–H bonds has attracted intensive attention due......
Solvent Dependent Assembly,Structural Diversity and Topology Analysis in Two Novel Ni Coordination P
Solvent dependent assembly obtained two novel Ni coordination polymers with H_2 tbtpa and flexible 1,2-bix ligand(H_2tbt......
Cd/Mn(Ⅱ) Complexes with Heterocyclic Substituted 1,2,4-Triazole Ligands:Syntheses,Crystal Structures
Based on a 3-(pyridine-2-yl)-4H-1,2,4-triazole ligand(Hpytr), one 2D Cd(Ⅱ) coordination polymer [Cd I(pytr)]_n(1) and o......
Despite its four valence electrons,carbon can at most form triple bond in ordinary organic complexes.Quadruple bonds for......
Enantioselective Alternating Copolymerization of Propylene with Carbon Monoxide Using Cationic Palla
Enantioselective alternating copolymerization of carbon monoxide with propylene was carried out using palladium catalyst......
Investigation on tribological behaviors of the modified UHMWPE with different structures of Schiff b
Investigation on the law of tribological modifying activity influenced by structure of additives will make prediction an......
Gene transfer into primary rat hepatocytes was performed by employing cationic liposome as DNA carrier and the specific......
1 General outline The Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, located in the Shanghai Inst......
The hydrogen bonding interactions between N-methylformamide and primary,secondary,and tertiary alcohols have been studie......
The title compound [Mn(DPMT)2Cl2(H2O)2] (DPMT = 1-[[2-(2,4-dichlorophenyl)- 1,3-dioxolan-2-yl]methyl]-1H-1,2,4-triazole)......
Formation and Characterization of Pd,Pt and Pd-Pt Alloy Films on Polyimide by Catalyst-Enhanced Chem
Platinum, palladium and their alloy films on polyimide were formed by catalyst-enhanced chemical vapor deposition (CVD) ......
SYNTHESIS,CHARACTERIZATION,THERMAL DEGRADATION AND ELECTRICAL CONDUCTIVITY OF OLIGO[2-(2-HYDROXYPHEN
The oxidative polycondensation reaction conditions of 2-[(2-hydroxyphenyliminomethylbenzylidene)amino- phenol](2-HPIMBAP......
A new cerium complex,(C7H8)[Ce(C7H3NO5)2(H2O)3]·2H2O or (C7H8)[Ce(HChel)2-(H2O)3]·2H2O (1,H3Chel = 4-hydroxypyridine-2......
The radioactive isotope tracer and ion exchange balanced method was used to study the stability of 109Cd, 65 Zn complex......
Relationship Between Grain Boundary Segregation of Antimony and Temper Embrittlement in Titanium-Dop
The antimony segregation at grain boundary was observed and the temper embrittlement in titanium-doped nickel-chromium s......
STUDIES ON ADDITION OF (μ-ALKYLTHIO)-(μ-HALOMAGNESIUMTHIO)HEXACARBONY-DIIRON WITH α,β-UNSATURATED OR
Through addition of (μ-alkylthio)(μ-halomagnesiumthio)hexacarbonyldiiron, (μ-RS)(ν-XMgS)Fe_2(CO)_6,to α,β-unsatur......
本论文合成了吡罗昔康和稀土金属镧的配合物,通过紫外光谱、红外光谱、元素分析、电导率、差热一热重等方法对其进行了表征,最后确......
合成了三氟乙酰丙酮(HTTA)与稀土离子Y(Ⅲ)、Er(Ⅲ)和Nd(Ⅲ)的配合物,并测定了它们的配位数及稳定常数,结果显示这四种配合物的配......
以1,1'-二茂铁双甲酸为配体,与Cd(II)作用合成了一个新配合物{[Cd(O2CFc CO2)2]·CH3CH2OH}n(Fc=ferrocene),并使用X-单晶衍射仪对其......
报道了5-[(对-N-酪氨酸丁氧基)苯基]-10,15,20-三(对-氯苯基)卟啉(H2L)及其配合物MLC1(M=Co,Fe,Mn)的合成,经元素分析、UV-cis、荧光光谱、IR和^1HNMR等结构表征。催化实验发现除配体外,3种配合物......
报道了一类含吡啶的新型大环席夫碱与第Ⅱ主族元素配合物的合成,它们的结构经元素分析、IR和′HNMR表征。......
本文对X·C2H2[X=(CH3)3N、NH3、(CH3)2O和CH3(N)及(NH3)2·C2H2]五种分子间氢键络合物体系进行了振动光谱研究。用MNDO方法对这五......
本文鲁士蓝类、杂化型普鲁士蓝类及其他类型氰基桥联配合物的分类、结构及其磁性质,并重点介绍了氰基桥联单分子磁体的最新研究成......
合成了未见文献报道的2-羟基苯甲醛缩(5,5)-二甲基-1,3-二氧杂己内硫代磷酰肼席夫碱配体及与Cu(Ⅱ)、Ni(Ⅱ)金属的配合物.这些化合......
利用紫外(UV)和圆二色(CD)光谱对Y-edta和La-edta配合物与DNA的相互作用进行了研究,并加以比较,同时考察了不同浓度、反应时间、不同缓冲......
文章报道了2,2’-间苯二甲硫基二乙酸和过渡金属铜(Ⅱ)、镉(Ⅱ)、镍(Ⅱ)配合物的合成,经元素分析、ICP发射光谱、红外光谱、核磁共振谱、差......
合成了一种新的锌氨基酸混配体配合物并用具有恒定温度环境反应热量计测定了配合物和反应物在298.2K条件下溶解在2 mol/L HCl溶液......
Schiff碱及其配合物具有特殊的结构和性质。文章以邻苯二甲醛(OPA)和氨基硫脲为原料,在不同反应条件下合成出一种对称的邻苯二甲醛双......
合成了5,10,15,20-四(对-十八酰氧基)苯基卟啉及其Mn(Ⅲ), Fe(Ⅲ), Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ)和Zn(Ⅱ)配合物, 用元素分析和紫外-可......
采用改进的邻苯三酚自氧化法研究了新型邻菲罗啉桥联多胺配体及其配合物对超氧阴离子的抑制作用,结果表明测试的所有配体及Cu^2+、Zn......
StudiesontheBindingofTris(1,10-phenanthroline)Nickel(Ⅱ)toCalfThymusDNAJINLan,YANGPin..andLIQing-shan(StateKeyLaboratoryofCoor.........
IntroductionThecontroleddesignofsolid-statearchitecturesandcrystalengineeringhascurrentlybeenrecognizedasoneofthemostimportan.........
A novel sensitizer with imidazole zinc porphyrin as electron donor has been synthesized. The structure has been characte......
采用锡粉、苄基氯为原料,二甲苯为溶剂,少量水作催化剂,直接合成了二苄基二氯化锡(1),得率为90%。还合成了其三苯基氧化膦配合物(2),得率为95%。对(1)、......